 |
 |
| Primera | 03/01/2022 | Villarreal CF | - | Levante UD | 5:0 | 13.462 |
| Primera | 09/01/2022 | Villarreal CF | - | Atlético Madrid | 2:2 | 14.127 |
| Primera | 22/01/2022 | Villarreal CF | - | RCD Mallorca | 3:0 | 13.207 |
| Primera | 12/02/2022 | Villarreal CF | - | Real Madrid | 0:0 | 17.894 |
| Ch. League | 22/02/2022 | Villarreal CF | - | Juventus | 1:1 | 17.686 |
| Primera | 27/02/2022 | Villarreal CF | - | Espanyol Barcelona | 5:1 | 15.600 |
| Primera | 12/03/2022 | Villarreal CF | - | RC Celta | 1:0 | 14.929 |
| Ch. League | 06/04/2022 | Villarreal CF | - | Bayern München | 1:0 | 21.626 |
| Primera | 09/04/2022 | Villarreal CF | - | Athletic Club | 1:1 | 16.603 |
| Primera | 19/04/2022 | Villarreal CF | - | Valencia CF | 2:0 | 13.570 |
| Ch. League | 03/05/2022 | Villarreal CF | - | Liverpool FC | 2:3 | 23.665 |
| Primera | 08/05/2022 | Villarreal CF | - | Sevilla FC | 1:1 | 17.461 |
| Primera | 15/05/2022 | Villarreal CF | - | Real Sociedad | 1:2 | 16.689 |
| Primera | 04/09/2022 | Villarreal CF | - | Elche CF | 4:0 | 13.915 |
| Primera | 31/12/2022 | Villarreal CF | - | Valencia CF | 2:1 | 19.247 |
Spain