| 3. Round | 25/01/2022 | Portimonense SC [U23] | - | Rio Ave FC [U23] | 0:1 | ||||
| 4. Round | 31/01/2022 | Sporting Braga [U23] | - | Rio Ave FC [U23] | 4:0 |  |
| 3. Round | 25/01/2022 | Portimonense SC [U23] | - | Rio Ave FC [U23] | 0:1 | ||||
| 4. Round | 31/01/2022 | Sporting Braga [U23] | - | Rio Ave FC [U23] | 4:0 | |
| Agostinho Azevedo Magalhães | |
| Born: | 01.07.2000 |
| Place of birth: |
Bissau, 
Guinea-Bissau |
| Nationality: |
Guinea-Bissau
Portugal |
| Height: | 184 cm |
| Weight: | 76 kg |
| Position(s): | Centre Forward Left Winger |
| Foot: | right |