| 1. Round | 15/09/2005 | AJ Auxerre | - | Levski Sofia | 2:1 | ||||
| 1. Round | 29/09/2005 | Levski Sofia | - | AJ Auxerre | 1:0 | ||||
| Group F | 24/11/2005 | CSKA Moskva | - | Levski Sofia | 2:1 | ||||
| Group F | 01/12/2005 | Levski Sofia | - | Olympique Marseille | 1:0 | ||||
| Group F | 14/12/2005 | sc Heerenveen | - | Levski Sofia | 2:1 | ||||
| Round of 16 | 09/03/2006 | Udinese Calcio | - | Levski Sofia | 0:0 | ||||
| Round of 16 | 16/03/2006 | Levski Sofia | - | Udinese Calcio | 2:1 | ||||
| Quarter-finals | 30/03/2006 | Levski Sofia | - | FC Schalke 04 | 1:3 | ||||
| Quarter-finals | 06/04/2006 | FC Schalke 04 | - | Levski Sofia | 1:1 |  |
Bulgaria