| 1. Round | 11/08/2013 | FC Schalke 04 | - | Hamburger SV | 3:3 | ||||
| 2. Round | 17/08/2013 | VfL Wolfsburg | - | FC Schalke 04 | 4:0 | ||||
| 4. Round | 31/08/2013 | FC Schalke 04 | - | Bayer Leverkusen | 2:0 | ||||
| 5. Round | 14/09/2013 | 1. FSV Mainz 05 | - | FC Schalke 04 | 0:1 |  |
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| 6. Round | 21/09/2013 | FC Schalke 04 | - | Bayern München | 0:4 | ||||
| 7. Round | 28/09/2013 | 1899 Hoffenheim | - | FC Schalke 04 | 3:3 | ||||
| 8. Round | 05/10/2013 | FC Schalke 04 | - | FC Augsburg | 4:1 | |
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| 9. Round | 19/10/2013 | Eintracht Braunschweig | - | FC Schalke 04 | 2:3 | |
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| 10. Round | 26/10/2013 | FC Schalke 04 | - | Borussia Dortmund | 1:3 | ||||
| 11. Round | 02/11/2013 | Hertha BSC | - | FC Schalke 04 | 0:2 | ||||
| 12. Round | 09/11/2013 | FC Schalke 04 | - | Werder Bremen | 3:1 | ||||
| 13. Round | 23/11/2013 | Eintracht Frankfurt | - | FC Schalke 04 | 3:3 | ||||
| 14. Round | 30/11/2013 | FC Schalke 04 | - | VfB Stuttgart | 3:0 | ||||
| 15. Round | 07/12/2013 | Bor. Mönchengladbach | - | FC Schalke 04 | 2:1 | |
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| 17. Round | 21/12/2013 | 1. FC Nürnberg | - | FC Schalke 04 | 0:0 | ||||
| 18. Round | 26/01/2014 | Hamburger SV | - | FC Schalke 04 | 0:3 | |
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| 20. Round | 09/02/2014 | FC Schalke 04 | - | Hannover 96 | 2:0 |
Japan
