| 2. Round | 08/09/1995 | FC Barcelona | - | CP Mérida | 2:2 | ||||
| 3. Round | 16/09/1995 | Real Zaragoza | - | FC Barcelona | 0:3 |  |
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| 5. Round | 30/09/1995 | Real Madrid | - | FC Barcelona | 1:1 | |
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| 6. Round | 04/10/1995 | FC Barcelona | - | Real Oviedo | 4:1 | |
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| 7. Round | 07/10/1995 | Real Betis | - | FC Barcelona | 1:5 | |
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| 8. Round | 14/10/1995 | FC Barcelona | - | Athletic Club | 4:1 | ||||
| 10. Round | 27/10/1995 | SD Compostela | - | FC Barcelona | 2:1 | |
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| 12. Round | 11/11/1995 | CD Tenerife | - | FC Barcelona | 1:1 | ||||
| 13. Round | 17/11/1995 | FC Barcelona | - | Albacete | 3:0 | ||||
| 14. Round | 24/11/1995 | Real Sociedad | - | FC Barcelona | 1:1 | ||||
| 16. Round | 08/12/1995 | Atlético Madrid | - | FC Barcelona | 3:1 | ||||
| 18. Round | 19/12/1995 | Sevilla FC | - | FC Barcelona | 1:0 | ||||
| 23. Round | 24/01/1996 | CP Mérida | - | FC Barcelona | 0:0 | ||||
| 26. Round | 09/02/1996 | FC Barcelona | - | Real Madrid | 3:0 | ||||
| 36. Round | 12/04/1996 | Racing Santander | - | FC Barcelona | 1:1 | ||||
| 38. Round | 27/04/1996 | Sporting Gijón | - | FC Barcelona | 0:3 | ||||
| 41. Round | 18/05/1996 | FC Barcelona | - | RC Celta | 3:2 | ||||
| 42. Round | 25/05/1996 | Deportivo La Coruña | - | FC Barcelona | 2:2 |
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