| 2. Round | 26/08/2000 | FC Utrecht | - | PSV Eindhoven | 1:3 | ||||
| 3. Round | 04/09/2000 | PSV Eindhoven | - | Willem II | 2:2 |  |
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| 4. Round | 07/09/2000 | Fortuna Sittard | - | PSV Eindhoven | 0:3 | |
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| 7. Round | 13/10/2000 | PSV Eindhoven | - | NEC Nijmegen | 0:0 | ||||
| 12. Round | 17/11/2000 | sc Heerenveen | - | PSV Eindhoven | 1:4 | ||||
| 8. Round | 11/12/2000 | RKC Waalwijk | - | PSV Eindhoven | 1:1 | ||||
| 18. Round | 16/12/2000 | AZ Alkmaar | - | PSV Eindhoven | 0:5 | ||||
| 18. Round | 20/12/2000 | PSV Eindhoven | - | Fortuna Sittard | 1:1 |
Brazil