| 3. Round | 25/01/2022 | Portimonense SC [U23] | - | Rio Ave FC [U23] | 0:1 | ||||
| 4. Round | 31/01/2022 | Sporting Braga [U23] | - | Rio Ave FC [U23] | 4:0 | ||||
| 7. Round | 24/02/2022 | SL Benfica [U23] | - | Rio Ave FC [U23] | 0:0 |
| 3. Round | 25/01/2022 | Portimonense SC [U23] | - | Rio Ave FC [U23] | 0:1 | ||||
| 4. Round | 31/01/2022 | Sporting Braga [U23] | - | Rio Ave FC [U23] | 4:0 | ||||
| 7. Round | 24/02/2022 | SL Benfica [U23] | - | Rio Ave FC [U23] | 0:0 |
| Darlan Santos Rufino de Oliveira | |
| Born: | 18.06.2001 |
| Place of birth: |
Paraíba, 
Brazil |
| Nationality: |
Brazil
|
| Height: | 190 cm |
| Weight: | 74 kg |
| Position(s): | Centre Back |
| Foot: | left |