| 1. Round | 17/08/2007 | Carabobo FC | - | El Nacional | 0:1 | ||||
| 1. Round | 29/08/2007 | El Nacional | - | Carabobo FC | 4:0 | ||||
| 2. Round | 05/09/2007 | El Nacional | - | Olmedo | 2:0 | ||||
| 2. Round | 12/09/2007 | Olmedo | - | El Nacional | 0:1 | ||||
| Round of 16 | 21/09/2007 | Defensor Sporting | - | El Nacional | 3:0 | ||||
| Round of 16 | 05/10/2007 | El Nacional | - | Defensor Sporting | 2:0 |  |
Ecuador