| 2. Round | 14/09/2008 | Villarreal CF | - | Deportivo La Coruña | 1:0 | ||||
| 3. Round | 21/09/2008 | CD Numancia | - | Villarreal CF | 1:2 | ||||
| 5. Round | 27/09/2008 | Sporting Gijón | - | Villarreal CF | 0:1 | ||||
| 9. Round | 01/11/2008 | Athletic Club | - | Villarreal CF | 1:4 | ||||
| 13. Round | 30/11/2008 | Recreativo Huelva | - | Villarreal CF | 1:2 | ||||
| 18. Round | 10/01/2009 | Valencia CF | - | Villarreal CF | 3:3 |
Brazil