| 1. Round | 12/08/2023 | Athletic Club | - | Real Madrid | 0:2 | ||||
| 2. Round | 19/08/2023 | CA Osasuna | - | Athletic Club | 0:2 | ||||
| 3. Round | 27/08/2023 | Athletic Club | - | Real Betis | 4:2 | ||||
| 11. Round | 29/10/2023 | Athletic Club | - | Valencia CF | 2:2 | ||||
| 26. Round | 25/02/2024 | Real Betis | - | Athletic Club | 3:1 |  |
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| 27. Round | 03/03/2024 | Athletic Club | - | FC Barcelona | 0:0 | |
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| 34. Round | 03/05/2024 | Getafe CF | - | Athletic Club | 0:2 | ||||
| 36. Round | 15/05/2024 | RC Celta | - | Athletic Club | 2:1 | ||||
| 38. Round | 25/05/2024 | Rayo Vallecano | - | Athletic Club | 0:1 |
Spain