| 2. Round | 07/08/2022 | Slavia Praha | - | FC Trinity Zlín | 4:1 |  |
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| 3. Round | 14/08/2022 | FK Jablonec | - | Slavia Praha | 2:3 |  |
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| 5. Round | 28/08/2022 | Zbrojovka Brno | - | Slavia Praha | 0:4 | ||||
| 6. Round | 31/08/2022 | Slavia Praha | - | FK Teplice | 6:0 | |
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| 7. Round | 04/09/2022 | 1. FC Slovácko | - | Slavia Praha | 1:1 | ||||
| 8. Round | 11/09/2022 | Slavia Praha | - | Dynamo České Budějovice | 6:1 | |
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| 17. Round | 29/01/2023 | Slavia Praha | - | FK Jablonec | 5:1 | ||||
| 19. Round | 11/02/2023 | Slavia Praha | - | Zbrojovka Brno | 2:0 | ||||
| 20. Round | 18/02/2023 | FK Teplice | - | Slavia Praha | 1:1 | |
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| 21. Round | 26/02/2023 | Slavia Praha | - | 1. FC Slovácko | 2:0 | ||||
| 22. Round | 05/03/2023 | Dynamo České Budějovice | - | Slavia Praha | 1:0 | ||||
| 23. Round | 11/03/2023 | Slavia Praha | - | Viktoria Plzeň | 2:1 | |
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| 25. Round | 01/04/2023 | Slavia Praha | - | Sigma Olomouc | 4:0 | |
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| 26. Round | 09/04/2023 | FK Mladá Boleslav | - | Slavia Praha | 1:1 | |
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| 27. Round | 15/04/2023 | AC Sparta Praha | - | Slavia Praha | 3:3 | |
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| 28. Round | 22/04/2023 | Slavia Praha | - | Bohemians Praha 1905 | 3:0 | ||||
| 29. Round | 25/04/2023 | Baník Ostrava | - | Slavia Praha | 0:2 | ||||
| 30. Round | 30/04/2023 | Slavia Praha | - | FC Hradec Králové | 1:1 |
Slovakia