| Group A | 08/09/2022 | PSV Eindhoven | - | FK Bodø/Glimt | 1:1 | ||||
| Group A | 06/10/2022 | FC Zürich | - | PSV Eindhoven | 1:5 | ||||
| Group A | 13/10/2022 | PSV Eindhoven | - | FC Zürich | 5:0 |  |
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| Group A | 20/10/2022 | Arsenal FC | - | PSV Eindhoven | 1:0 | ||||
| Group A | 27/10/2022 | PSV Eindhoven | - | Arsenal FC | 2:0 | |
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| Group A | 03/11/2022 | FK Bodø/Glimt | - | PSV Eindhoven | 1:2 | ||||
| Play-offs | 16/02/2023 | Sevilla FC | - | PSV Eindhoven | 3:0 | ||||
| Play-offs | 23/02/2023 | PSV Eindhoven | - | Sevilla FC | 2:0 |
Netherlands