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| 1st(1st leg) | FC Barcelona | - | Manchester United | 2:2 (0:0) | ||
| 2nd (2nd leg) | Manchester United | - | FC Barcelona | 2:1 (0:1) | ||
| 1st(1st leg): 16/02/2023 17:45 | 2nd (2nd leg): 23/02/2023 20:00 | Winner: Manchester United | ||||
| 1st(1st leg) | Shakhtar Donetsk | - | Stade Rennais | 2:1 (2:0) | ||
| 2nd (2nd leg) | Stade Rennais | - | Shakhtar Donetsk | 4:5 (0:0, 1:0, 2:1) pso | ||
| 1st(1st leg): 16/02/2023 17:45 | 2nd (2nd leg): 23/02/2023 20:00 | Winner: Shakhtar Donetsk | ||||
| 1st(1st leg) | AFC Ajax | - | 1. FC Union Berlin | 0:0 (0:0) | ||
| 2nd (2nd leg) | 1. FC Union Berlin | - | AFC Ajax | 3:1 (2:0) | ||
| 1st(1st leg): 16/02/2023 17:45 | 2nd (2nd leg): 23/02/2023 20:00 | Winner: 1. FC Union Berlin | ||||
| 1st(1st leg) | RB Salzburg | - | AS Roma | 1:0 (0:0) | ||
| 2nd (2nd leg) | AS Roma | - | RB Salzburg | 2:0 (2:0) | ||
| 1st(1st leg): 16/02/2023 17:45 | 2nd (2nd leg): 23/02/2023 20:00 | Winner: AS Roma | ||||
| 1st(1st leg) | Juventus | - | FC Nantes | 1:1 (1:0) | ||
| 2nd (2nd leg) | FC Nantes | - | Juventus | 0:3 (0:2) | ||
| 1st(1st leg): 16/02/2023 20:00 | 2nd (2nd leg): 23/02/2023 17:45 | Winner: Juventus | ||||
| 1st(1st leg) | Sporting CP | - | FC Midtjylland | 1:1 (0:0) | ||
| 2nd (2nd leg) | FC Midtjylland | - | Sporting CP | 0:4 (0:1) | ||
| 1st(1st leg): 16/02/2023 20:00 | 2nd (2nd leg): 23/02/2023 17:45 | Winner: Sporting CP | ||||
| 1st(1st leg) | Bayer Leverkusen | - | AS Monaco | 2:3 (0:1) | ||
| 2nd (2nd leg) | AS Monaco | - | Bayer Leverkusen | 3:5 (1:2, 2:3, 2:3) pso | ||
| 1st(1st leg): 16/02/2023 20:00 | 2nd (2nd leg): 23/02/2023 17:45 | Winner: Bayer Leverkusen | ||||
| 1st(1st leg) | Sevilla FC | - | PSV Eindhoven | 3:0 (1:0) | ||
| 2nd (2nd leg) | PSV Eindhoven | - | Sevilla FC | 2:0 (0:0) | ||
| 1st(1st leg): 16/02/2023 20:00 | 2nd (2nd leg): 23/02/2023 17:45 | Winner: Sevilla FC | ||||
