| 1. Round | 26/08/2007 | Espanyol Barcelona | - | Real Valladolid | 0:1 | ||||
| 2. Round | 02/09/2007 | Real Betis | - | Espanyol Barcelona | 2:2 | ||||
| 4. Round | 22/09/2007 | Recreativo Huelva | - | Espanyol Barcelona | 2:1 | ||||
| 5. Round | 25/09/2007 | Sevilla FC | - | Espanyol Barcelona | 2:3 | ||||
| 6. Round | 30/09/2007 | Espanyol Barcelona | - | Deportivo La Coruña | 1:0 | ||||
| 7. Round | 06/10/2007 | Valencia CF | - | Espanyol Barcelona | 1:2 | ||||
| 8. Round | 20/10/2007 | Espanyol Barcelona | - | Real Madrid | 2:1 | ||||
| 9. Round | 27/10/2007 | RCD Mallorca | - | Espanyol Barcelona | 2:2 | ||||
| 12. Round | 11/11/2007 | Espanyol Barcelona | - | Athletic Club | 2:1 |
Brazil