| 3. Round | 26/02/2000 | Rosario Central | - | Newell's Old Boys | 1:1 | ||||
| 4. Round | 04/03/2000 | Newell's Old Boys | - | Colón de Santa Fe | 3:3 | ||||
| 5. Round | 11/03/2000 | Estudiantes | - | Newell's Old Boys | 1:3 | ||||
| 9. Round | 10/04/2000 | Argentinos Juniors | - | Newell's Old Boys | 1:4 | ||||
| 13. Round | 26/05/2000 | Newell's Old Boys | - | Boca Juniors | 1:0 | ||||
| 16. Round | 23/06/2000 | Talleres de Córdoba | - | Newell's Old Boys | 1:3 | ||||
| 18. Round | 09/07/2000 | Chacarita Juniors | - | Newell's Old Boys | 0:1 | ||||
| 19. Round | 16/07/2000 | Newell's Old Boys | - | Ferro Carril Oeste | 2:0 |
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Italy