| 1. Round | 10/08/2001 | Lommelse SK | - | RWD Molenbeek | 1:0 |  |
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| 2. Round | 17/08/2001 | RWD Molenbeek | - | RSC Charleroi | 0:1 | ||||
| 3. Round | 25/08/2001 | Standard Liège | - | RWD Molenbeek | 2:1 | ||||
| 4. Round | 08/09/2001 | RWD Molenbeek | - | Germinal Beerschot | 2:2 | ||||
| 5. Round | 14/09/2001 | RWD Molenbeek | - | Sint-Truidense VV | 1:2 | ||||
| 6. Round | 21/09/2001 | Excelsior Mouscron | - | RWD Molenbeek | 4:1 | ||||
| 9. Round | 12/10/2001 | RWD Molenbeek | - | KSK Beveren | 3:0 |  |
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| 10. Round | 19/10/2001 | Royal Antwerp FC | - | RWD Molenbeek | 1:2 | |
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| 12. Round | 02/11/2001 | RSC Anderlecht | - | RWD Molenbeek | 2:2 | ||||
| 13. Round | 24/11/2001 | RWD Molenbeek | - | KRC Genk | 2:5 | ||||
| 14. Round | 27/11/2001 | K.S.C. Eendracht Aalst | - | RWD Molenbeek | 2:4 | ||||
| 16. Round | 08/12/2001 | RWD Molenbeek | - | Club Brugge KV | 2:3 | ||||
| 18. Round | 11/01/2002 | RWD Molenbeek | - | Lommelse SK | 0:1 | ||||
| 20. Round | 26/01/2002 | RWD Molenbeek | - | Standard Liège | 2:1 | ||||
| 21. Round | 01/02/2002 | Germinal Beerschot | - | RWD Molenbeek | 2:2 | |
Czech Republic