| 1. Round | 14/09/2020 | Sheffield United | - | Wolverhampton Wanderers | 0:2 |  |
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| 2. Round | 21/09/2020 | Wolverhampton Wanderers | - | Manchester City | 1:3 | ||||
| 5. Round | 19/10/2020 | Leeds United | - | Wolverhampton Wanderers | 0:1 | ||||
| 6. Round | 25/10/2020 | Wolverhampton Wanderers | - | Newcastle United | 1:1 | ||||
| 8. Round | 08/11/2020 | Leicester City | - | Wolverhampton Wanderers | 1:0 | ||||
| 10. Round | 29/11/2020 | Arsenal FC | - | Wolverhampton Wanderers | 1:2 | ||||
| 11. Round | 06/12/2020 | Liverpool FC | - | Wolverhampton Wanderers | 4:0 | ||||
| 12. Round | 12/12/2020 | Wolverhampton Wanderers | - | Aston Villa | 0:1 | ||||
| 13. Round | 15/12/2020 | Wolverhampton Wanderers | - | Chelsea FC | 2:1 | ||||
| 15. Round | 27/12/2020 | Wolverhampton Wanderers | - | Tottenham Hotspur | 1:1 | |
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| 24. Round | 14/02/2021 | Southampton FC | - | Wolverhampton Wanderers | 1:2 | ||||
| 25. Round | 19/02/2021 | Wolverhampton Wanderers | - | Leeds United | 1:0 | ||||
| 38. Round | 23/05/2021 | Wolverhampton Wanderers | - | Manchester United | 1:2 |
Brazil