| 1. Round | 30/07/1999 | Toulouse FC | - | SM Caen | 0:1 | ||||
| 4. Round | 16/08/1999 | FC Lorient | - | Toulouse FC | 1:1 | ||||
| 5. Round | 20/08/1999 | Toulouse FC | - | FC Gueugnon | 2:0 | ||||
| 6. Round | 27/08/1999 | FC Sochaux | - | Toulouse FC | 0:2 | ||||
| 7. Round | 02/09/1999 | Toulouse FC | - | Lille OSC | 0:2 | ||||
| 8. Round | 06/09/1999 | Amiens SC | - | Toulouse FC | 1:1 | ||||
| 9. Round | 10/09/1999 | Toulouse FC | - | EA Guingamp | 1:2 | ||||
| 10. Round | 18/09/1999 | Stade Lavallois | - | Toulouse FC | 0:3 |  |
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| 21. Round | 03/12/1999 | ASOA Valence | - | Toulouse FC | 0:2 | ||||
| 24. Round | 25/01/2000 | Toulouse FC | - | FC Sochaux | 3:0 | ||||
| 33. Round | 14/04/2000 | Louhans-Cuiseaux | - | Toulouse FC | 1:2 | ||||
| 34. Round | 20/04/2000 | US Créteil-Lusitanos | - | Toulouse FC | 3:1 | |
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| 38. Round | 19/05/2000 | SM Caen | - | Toulouse FC | 1:1 |
France