| Group 8 | 17/02/2006 | Libertad | - | River Plate | 2:0 | ||||
| Group 8 | 02/03/2006 | Paulista - SP | - | Libertad | 0:0 | ||||
| Group 8 | 23/03/2006 | Libertad | - | El Nacional | 4:1 |  |
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| Group 8 | 31/03/2006 | El Nacional | - | Libertad | 1:1 | ||||
| Group 8 | 12/04/2006 | Libertad | - | Paulista - SP | 1:0 | ||||
| Round of 16 | 28/04/2006 | UANL Tigres | - | Libertad | 0:0 | ||||
| Round of 16 | 04/05/2006 | Libertad | - | UANL Tigres | 5:3 pso | ||||
| Quarter-finals | 12/05/2006 | River Plate | - | Libertad | 2:2 | ||||
| Quarter-finals | 19/07/2006 | Libertad | - | River Plate | 3:1 | |
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| Semi-finals | 28/07/2006 | Libertad | - | Internacional | 0:0 | ||||
| Semi-finals | 04/08/2006 | Internacional | - | Libertad | 2:0 |  |
Uruguay