| 1. Round | 13/07/2013 | Metalurg Zaporizhya | - | FK Illichivets | 0:1 | ||||
| 2. Round | 19/07/2013 | FK Illichivets | - | Dnipro Dnipropetrovsk | 0:2 | ||||
| 3. Round | 26/07/2013 | Metalist Kharkiv | - | FK Illichivets | 2:0 | ||||
| 4. Round | 02/08/2013 | FK Illichivets | - | Karpaty Lviv | 1:1 | ||||
| 5. Round | 10/08/2013 | Vorskla Poltava | - | FK Illichivets | 1:0 | ||||
| 6. Round | 17/08/2013 | FK Illichivets | - | Metalurh Donetsk | 3:0 | ||||
| 7. Round | 23/08/2013 | Arsenal Kiev | - | FK Illichivets | annull. | ||||
| 8. Round | 01/09/2013 | Chernomorets Odessa | - | FK Illichivets | 1:0 | ||||
| 9. Round | 14/09/2013 | FK Illichivets | - | Zorya Lugansk | 1:0 | ||||
| 10. Round | 20/09/2013 | Volyn Lutsk | - | FK Illichivets | 1:0 | ||||
| 12. Round | 06/10/2013 | PFK Sevastopol | - | FK Illichivets | 0:1 | ||||
| 13. Round | 19/10/2013 | FK Illichivets | - | Shakhtar Donetsk | 1:3 | ||||
| 14. Round | 27/10/2013 | Dinamo Kiev | - | FK Illichivets | 1:0 |  |
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| 15. Round | 02/11/2013 | FK Illichivets | - | Tavriya Simferopol (1958-2014) | 1:2 | ||||
| 16. Round | 08/11/2013 | FK Illichivets | - | Metalurg Zaporizhya | 3:1 | |
Russia