| 2. Round | 21/07/2013 | Volyn Lutsk | - | Tavriya Simferopol (1958-2014) | 1:0 | ||||
| 3. Round | 27/07/2013 | Metalurg Zaporizhya | - | Volyn Lutsk | 3:0 | ||||
| 4. Round | 03/08/2013 | Volyn Lutsk | - | Dnipro Dnipropetrovsk | 1:3 |  |
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| 5. Round | 10/08/2013 | Metalist Kharkiv | - | Volyn Lutsk | 4:0 | ||||
| 7. Round | 24/08/2013 | Vorskla Poltava | - | Volyn Lutsk | 3:3 | |
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| 8. Round | 01/09/2013 | Volyn Lutsk | - | Metalurh Donetsk | 1:0 |  |
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| 9. Round | 13/09/2013 | Arsenal Kiev | - | Volyn Lutsk | annull. | ||||
| 10. Round | 20/09/2013 | Volyn Lutsk | - | FK Illichivets | 1:0 |  |
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| 12. Round | 06/10/2013 | Chernomorets Odessa | - | Volyn Lutsk | 0:0 | ||||
| 13. Round | 18/10/2013 | Volyn Lutsk | - | Hoverla Uzhgorod | 0:1 | |
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| 14. Round | 27/10/2013 | PFK Sevastopol | - | Volyn Lutsk | 2:1 | |
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| 15. Round | 01/11/2013 | Volyn Lutsk | - | Shakhtar Donetsk | 2:0 | ||||
| 16. Round | 10/11/2013 | Volyn Lutsk | - | Dinamo Kiev | 1:4 |
Brazil
Italy