| 1. Round | 23/07/2022 | Sporting Charleroi | - | KAS Eupen | 3:1 | ||||
| 2. Round | 29/07/2022 | Union Saint-Gilloise | - | Sporting Charleroi | 1:0 | ||||
| 3. Round | 06/08/2022 | Sporting Charleroi | - | KV Oostende | 1:3 |  |
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| 9. Round | 17/09/2022 | Sporting Charleroi | - | KVC Westerlo | 2:3 | ||||
| 24. Round | 05/02/2023 | KV Mechelen | - | Sporting Charleroi | 2:2 | ||||
| 25. Round | 11/02/2023 | Sporting Charleroi | - | RFC Seraing | 3:0 | |
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| 26. Round | 18/02/2023 | KV Oostende | - | Sporting Charleroi | 0:0 | ||||
| 27. Round | 26/02/2023 | Sporting Charleroi | - | Sint-Truidense VV | 1:0 | ||||
| 28. Round | 04/03/2023 | KV Kortrijk | - | Sporting Charleroi | 0:1 | ||||
| 29. Round | 10/03/2023 | Sporting Charleroi | - | Oud-Heverlee Leuven | 0:1 | ||||
| 30. Round | 19/03/2023 | Royal Antwerp FC | - | Sporting Charleroi | 0:1 | ||||
| 31. Round | 01/04/2023 | KVC Westerlo | - | Sporting Charleroi | 2:3 | |
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| 32. Round | 08/04/2023 | Sporting Charleroi | - | SV Zulte Waregem | 3:2 | |
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| 33. Round | 14/04/2023 | Standard Liège | - | Sporting Charleroi | 3:1 | ||||
| 34. Round | 23/04/2023 | Sporting Charleroi | - | KRC Genk | 2:2 | |
Switzerland
Serbia