| 4. Round | 24/09/2006 | Getafe CF | - | Athletic Club | 0:0 |  |
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| 5. Round | 30/09/2006 | Athletic Club | - | FC Barcelona | 1:3 | ||||
| 9. Round | 05/11/2006 | Athletic Club | - | Racing Santander | 0:0 | ||||
| 10. Round | 11/11/2006 | Valencia CF | - | Athletic Club | 1:1 | |
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| 11. Round | 19/11/2006 | Espanyol Barcelona | - | Athletic Club | 3:2 | ||||
| 12. Round | 26/11/2006 | Athletic Club | - | Sevilla FC | 1:3 | ||||
| 22. Round | 11/02/2007 | Atlético Madrid | - | Athletic Club | 1:0 | ||||
| 23. Round | 18/02/2007 | Athletic Club | - | Getafe CF | 2:0 | |
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| 27. Round | 17/03/2007 | Athletic Club | - | CA Osasuna | 0:3 | ||||
| 29. Round | 07/04/2007 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 31. Round | 22/04/2007 | Sevilla FC | - | Athletic Club | 4:1 | ||||
| 33. Round | 06/05/2007 | Recreativo Huelva | - | Athletic Club | 0:0 | ||||
| 36. Round | 27/05/2007 | Athletic Club | - | RCD Mallorca | 1:0 | ||||
| 37. Round | 09/06/2007 | Villarreal CF | - | Athletic Club | 3:1 | |
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| 38. Round | 17/06/2007 | Athletic Club | - | Levante UD | 2:0 |
Spain