| 1. Round | 30/08/2009 | Athletic Club | - | Espanyol Barcelona | 1:0 | ||||
| 3. Round | 20/09/2009 | Athletic Club | - | Villarreal CF | 3:2 | ||||
| 5. Round | 26/09/2009 | Athletic Club | - | Sevilla FC | 0:4 | ||||
| 6. Round | 04/10/2009 | Real Valladolid | - | Athletic Club | 2:2 |  |
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| 8. Round | 25/10/2009 | Getafe CF | - | Athletic Club | 2:0 | |
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| 9. Round | 31/10/2009 | Athletic Club | - | Atlético Madrid | 1:0 | ||||
| 10. Round | 08/11/2009 | Racing Santander | - | Athletic Club | 0:2 |  |
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| 11. Round | 21/11/2009 | Athletic Club | - | FC Barcelona | 1:1 | ||||
| 12. Round | 29/11/2009 | UD Almería | - | Athletic Club | 1:4 |  |
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| 15. Round | 19/12/2009 | Athletic Club | - | CA Osasuna | 2:0 | ||||
| 20. Round | 30/01/2010 | Espanyol Barcelona | - | Athletic Club | 1:0 | ||||
| 28. Round | 25/03/2010 | Atlético Madrid | - | Athletic Club | 2:0 | ||||
| 32. Round | 15/04/2010 | Valencia CF | - | Athletic Club | 2:0 | ||||
| 34. Round | 26/04/2010 | CA Osasuna | - | Athletic Club | 0:0 | |
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| 38. Round | 15/05/2010 | Athletic Club | - | Deportivo La Coruña | 2:0 |
Spain