| 7. Round | 17/10/2010 | Athletic Club | - | Real Zaragoza | 2:1 |  |
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| 8. Round | 24/10/2010 | Sevilla FC | - | Athletic Club | 4:3 | ||||
| 9. Round | 31/10/2010 | Athletic Club | - | Getafe CF | 3:0 | ||||
| 10. Round | 07/11/2010 | Villarreal CF | - | Athletic Club | 4:1 | ||||
| 11. Round | 13/11/2010 | Athletic Club | - | UD Almería | 1:0 | ||||
| 12. Round | 20/11/2010 | Real Madrid | - | Athletic Club | 5:1 | ||||
| 16. Round | 18/12/2010 | Levante UD | - | Athletic Club | 1:2 | ||||
| 17. Round | 02/01/2011 | Athletic Club | - | Deportivo La Coruña | 1:2 |  |
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| 19. Round | 15/01/2011 | Athletic Club | - | Racing Santander | 2:1 | ||||
| 34. Round | 02/05/2011 | Espanyol Barcelona | - | Athletic Club | 2:1 |
Spain