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| 1st(1st leg) | Fluminense RJ | - | Athletico Paranaense | 2:4 (1:2) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Fluminense RJ | 3:2 (1:0) | ||
| 1st(1st leg): 12/10/2022 15:00 | 2nd (2nd leg): 18/10/2022 19:30 | Winner: Athletico Paranaense | ||||
| 1st(1st leg) | Palmeiras | - | Atlético Mineiro | 4:2 (0:1) | ||
| 2nd (2nd leg) | Atlético Mineiro | - | Palmeiras | 3:2 (1:1) | ||
| 1st(1st leg): 12/10/2022 20:00 | 2nd (2nd leg): 20/10/2022 19:45 | Winner: Palmeiras | ||||
| 1st(1st leg) | Fortaleza | - | Santos FC | 0:2 (0:0) | ||
| 2nd (2nd leg) | Santos FC | - | Fortaleza | 4:0 (2:0) | ||
| 1st(1st leg): 13/10/2022 19:00 | 2nd (2nd leg): 19/10/2022 19:00 | Winner: Santos FC | ||||
| 1st(1st leg) | Grêmio Porto Alegre | - | Vasco da Gama | 2:0 (1:0) | ||
| 2nd (2nd leg) | Vasco da Gama | - | Grêmio Porto Alegre | 1:2 (0:0) | ||
| 1st(1st leg): 13/10/2022 19:00 | 2nd (2nd leg): 21/10/2022 19:45 | Winner: Grêmio Porto Alegre | ||||
