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| 1st(1st leg) | Brasil de Pelotas - RS | - | Palmeiras | 0:3 (0:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Brasil de Pelotas - RS | 2:1 (0:0) | ||
| 1st(1st leg): 03/10/2022 19:30 | 2nd (2nd leg): 10/10/2022 19:00 | Winner: Palmeiras | ||||
| 1st(1st leg) | Internacional | - | Londrina - PR | 4:2 (2:1) | ||
| 2nd (2nd leg) | Londrina - PR | - | Internacional | 1:1 (0:0) | ||
| 1st(1st leg): 04/10/2022 19:00 | 2nd (2nd leg): 09/10/2022 14:00 | Winner: Internacional | ||||
| 1st(1st leg) | Fluminense RJ | - | Cruzeiro | 4:2 (2:1) | ||
| 2nd (2nd leg) | Cruzeiro | - | Fluminense RJ | 3:1 (3:1, 3:1) pso | ||
| 1st(1st leg): 04/10/2022 19:15 | 2nd (2nd leg): 10/10/2022 21:00 | Winner: Cruzeiro | ||||
| 1st(1st leg) | América - MG | - | Flamengo RJ | 0:1 (0:1) | ||
| 2nd (2nd leg) | Flamengo RJ | - | América - MG | 2:0 (0:0) | ||
| 1st(1st leg): 04/10/2022 20:00 | 2nd (2nd leg): 10/10/2022 19:00 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | Real Ariquemes - RO | - | Remo - PA | 1:1 (1:0) | ||
| 2nd (2nd leg) | Remo - PA | - | Real Ariquemes - RO | 3:2 (1:1) | ||
| 1st(1st leg): 04/10/2022 20:30 | 2nd (2nd leg): 11/10/2022 00:00 | Winner: Remo - PA | ||||
| 1st(1st leg) | ABC - RN | - | Fluminense - PI | 3:3 (2:2) | ||
| 2nd (2nd leg) | Fluminense - PI | - | ABC - RN | 2:0 (1:0) | ||
| 1st(1st leg): 05/10/2022 19:00 | 2nd (2nd leg): 09/10/2022 19:00 | Winner: Fluminense - PI | ||||
| 1st(1st leg) | Náutico - PE | - | Ceará - CE | 3:1 (2:1) | ||
| 2nd (2nd leg) | Ceará - CE | - | Náutico - PE | 3:2 (1:1, 3:1, 3:1) pso | ||
| 1st(1st leg): 05/10/2022 19:00 | 2nd (2nd leg): 08/10/2022 19:00 | Winner: Ceará - CE | ||||
| 1st(1st leg) | IAPE - MA | - | São Raimundo - RR | 3:1 (3:0) | ||
| 2nd (2nd leg) | São Raimundo - RR | - | IAPE - MA | 0:2 (0:1) | ||
| 1st(1st leg): 05/10/2022 19:30 | 2nd (2nd leg): 09/10/2022 21:00 | Winner: IAPE - MA | ||||
