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| 1st(1st leg) | Unión Española | - | Colo-Colo | 3:1 (0:1) | ||
| 2nd (2nd leg) | Colo-Colo | - | Unión Española | 0:2 (0:0) | ||
| 1st(1st leg): 28/11/2012 22:30 | 2nd (2nd leg): 02/12/2012 20:45 | Winner: Unión Española | ||||
| 1st(1st leg) | Huachipato | - | Rangers | 1:0 (0:0) | ||
| 2nd (2nd leg) | Rangers | - | Huachipato | 1:1 (0:0) | ||
| 1st(1st leg): 30/11/2012 00:15 | 2nd (2nd leg): 02/12/2012 23:00 | Winner: Huachipato | ||||
