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| 02/08/2023 | FC Trostianets | - | Real Pharma Odessa | dnp | ||
| 10:00 | FC Chernigov | - | Livyi Bereh | 1:2 (1:1) | ||
| 11:00 | Vast Mykolaiv | - | FSK Mariupol | 2:5 (0:3) | ||
| 12:00 | Druzhba Myrivka | - | Viktoriya Sumy | 1:2 (1:0) | ||
| 13:00 | Prykarpattya Ivano-Frankivsk | - | Karpaty Lviv | 2:1 (1:0) | ||
| 13:00 | FC Zviahel | - | Chaika Petropavlivska Borshchahivka | 5:0 (1:0) | ||
| 14:00 | Skala Stryi | - | FC Khust | 5:2 (3:0) | ||
| 14:00 | FK Nyva Vinnytsia | - | Ahrobiznes Volochysk | 0:1 (0:0, 0:0) aet | ||
| 14:00 | Hirnyk-Sport | - | SK Poltava | 1:0 (0:0, 0:0) aet | ||
| 14:00 | FK UCSA Tarasivka | - | FC Nyva Buzova | 4:3 (0:0, 1:1, 1:1) pso | ||
| 15:00 | Metalist Kharkiv | - | Epitsentr Kamianets-Podilskyi | 1:2 (0:0) | ||
| 15:00 | FK Podillya-Khmelnitskiy | - | Niva Ternopil | 2:3 (0:0, 0:0, 0:0) pso | ||
| 15:00 | Inhulets Petrove | - | Metalurg Zaporizhya | 4:3 (3:2) | ||
| 15:00 | FC Mykolaiv | - | FK Bukovina | 1:0 | ||
| 16:00 | FC Kudrivka | - | FK Kremin | 3:0 | ||
| 03/08/2023 | 14:00 | Lokomotiv Kiev | - | FC Dinaz Vyshhorod | 1:0 (0:0) |
