| Copa Libertadores | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 2 | : | 1 | |
| Away | 1 | 0 | 1 | 0 | 0 | : | 0 | |
| ∑ | 2 | 1 | 1 | 0 | 2 | : | 1 | |
| Serie A | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 4 | : | 0 | |
| Away | 1 | 0 | 1 | 0 | 2 | : | 2 | |
| ∑ | 2 | 1 | 1 | 0 | 6 | : | 2 | |
| overall | M. | W | D | L | goals | |||
| at home | 2 | 2 | 0 | 0 | 6 | : | 1 | |
| Away | 2 | 0 | 2 | 0 | 2 | : | 2 | |
| Neutral Place | 0 | 0 | 0 | 0 | 0 | : | 0 | |
| ∑ | 4 | 2 | 2 | 0 | 8 | : | 3 | |
| Copa Libertadores | |||||
| 1972 | Group 2 | América de Quito | - | Barcelona | 0:0 (0:0) |
| 1972 | Group 2 | Barcelona | - | América de Quito | 2:1 (0:0) |
| Serie A | |||||
| 2019 | 23. Round | Barcelona | - | América de Quito | 4:0 (3:0) |
| 2019 | 8. Round | América de Quito | - | Barcelona | 2:2 (1:0) |
|
For games that were decided on penalties the score after 120 minutes will be included in the ranking |
Ecuador 
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