| Copa Libertadores | M. | W | D | L | goals | |||
| at home | 1 | 0 | 1 | 0 | 0 | : | 0 | |
| Away | 1 | 0 | 1 | 0 | 1 | : | 1 | |
| ∑ | 2 | 0 | 2 | 0 | 1 | : | 1 | |
| Copa Merconorte | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 2 | : | 0 | |
| Away | 1 | 0 | 0 | 1 | 0 | : | 4 | |
| ∑ | 2 | 1 | 0 | 1 | 2 | : | 4 | |
| overall | M. | W | D | L | goals | |||
| at home | 2 | 1 | 1 | 0 | 2 | : | 0 | |
| Away | 2 | 0 | 1 | 1 | 1 | : | 5 | |
| Neutral Place | 0 | 0 | 0 | 0 | 0 | : | 0 | |
| ∑ | 4 | 1 | 2 | 1 | 3 | : | 5 | |
| Copa Libertadores | |||||
| 2013 | Group 1 | Barcelona | - | Deportivo Toluca | 0:0 (0:0) |
| 2013 | Group 1 | Deportivo Toluca | - | Barcelona | 1:1 (0:1) |
| Copa Merconorte | |||||
| 2000 | Group C | Deportivo Toluca | - | Barcelona | 4:0 (3:0) |
| 2000 | Group C | Barcelona | - | Deportivo Toluca | 2:0 (0:0) |
|
For games that were decided on penalties the score after 120 minutes will be included in the ranking |
Ecuador 
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