| 6. Round | 17/09/2022 | Athletic Club | - | Rayo Vallecano | 3:2 | ||||
| 7. Round | 30/09/2022 | Athletic Club | - | UD Almería | 4:0 | ||||
| 8. Round | 08/10/2022 | Sevilla FC | - | Athletic Club | 1:1 |  |
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| 10. Round | 18/10/2022 | Getafe CF | - | Athletic Club | 2:2 |  |
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| 11. Round | 23/10/2022 | FC Barcelona | - | Athletic Club | 4:0 | ||||
| 14. Round | 08/11/2022 | Athletic Club | - | Real Valladolid | 3:0 | |
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| 18. Round | 22/01/2023 | Athletic Club | - | Real Madrid | 0:2 | |
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| 19. Round | 29/01/2023 | RC Celta | - | Athletic Club | 1:0 | ||||
| 28. Round | 08/04/2023 | Espanyol Barcelona | - | Athletic Club | 1:2 | ||||
| 29. Round | 15/04/2023 | Athletic Club | - | Real Sociedad | 2:0 | ||||
| 30. Round | 22/04/2023 | UD Almería | - | Athletic Club | 1:2 | ||||
| 31. Round | 27/04/2023 | Athletic Club | - | Sevilla FC | 0:1 | ||||
| 32. Round | 01/05/2023 | RCD Mallorca | - | Athletic Club | 1:1 | ||||
| 33. Round | 04/05/2023 | Athletic Club | - | Real Betis | 0:1 | ||||
| 34. Round | 13/05/2023 | Villarreal CF | - | Athletic Club | 5:1 | |
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| 35. Round | 20/05/2023 | Athletic Club | - | RC Celta | 2:1 | ||||
| 38. Round | 04/06/2023 | Real Madrid | - | Athletic Club | 1:1 |
Spain
