| 1. Round | 30/07/2022 | Heart of Midlothian | - | Ross County FC | 2:1 | ||||
| 2. Round | 07/08/2022 | Hibernian FC | - | Heart of Midlothian | 1:1 | ||||
| 3. Round | 14/08/2022 | Heart of Midlothian | - | Dundee United | 4:1 | ||||
| 5. Round | 28/08/2022 | Heart of Midlothian | - | St. Johnstone FC | 3:2 | ||||
| 6. Round | 03/09/2022 | Livingston FC | - | Heart of Midlothian | 1:0 | ||||
| 8. Round | 18/09/2022 | Motherwell FC | - | Heart of Midlothian | 0:3 | ||||
| 9. Round | 01/10/2022 | Heart of Midlothian | - | Rangers FC | 0:4 | ||||
| 10. Round | 09/10/2022 | Kilmarnock FC | - | Heart of Midlothian | 2:2 | ||||
| 11. Round | 16/10/2022 | Aberdeen FC | - | Heart of Midlothian | 2:0 | ||||
| 12. Round | 22/10/2022 | Heart of Midlothian | - | Celtic FC | 3:4 | ||||
| 13. Round | 30/10/2022 | Ross County FC | - | Heart of Midlothian | 1:2 | ||||
| 14. Round | 06/11/2022 | Heart of Midlothian | - | Motherwell FC | 3:2 |  |
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| 15. Round | 09/11/2022 | Rangers FC | - | Heart of Midlothian | 1:0 | ||||
| 16. Round | 12/11/2022 | Heart of Midlothian | - | Livingston FC | 1:1 | ||||
| 17. Round | 17/12/2022 | Heart of Midlothian | - | Kilmarnock FC | 3:1 | ||||
| 18. Round | 24/12/2022 | Dundee United | - | Heart of Midlothian | 2:2 |
Scotland
