| 1. Round | 04/08/2012 | Heart of Midlothian | - | St. Johnstone FC | 2:0 | ||||
| 4. Round | 26/08/2012 | Aberdeen FC | - | Heart of Midlothian | 0:0 | ||||
| 5. Round | 02/09/2012 | Heart of Midlothian | - | Dundee FC | 0:1 | ||||
| 6. Round | 15/09/2012 | St. Mirren FC | - | Heart of Midlothian | 2:0 | ||||
| 7. Round | 22/09/2012 | Dundee United | - | Heart of Midlothian | 0:3 | ||||
| 8. Round | 29/09/2012 | Heart of Midlothian | - | Kilmarnock FC | 1:3 | ||||
| 17. Round | 08/12/2012 | Heart of Midlothian | - | Aberdeen FC | 2:0 | ||||
| 18. Round | 15/12/2012 | St. Johnstone FC | - | Heart of Midlothian | 2:2 | ||||
| 23. Round | 19/01/2013 | Celtic FC | - | Heart of Midlothian | 4:1 | ||||
| 32. Round | 30/03/2013 | Aberdeen FC | - | Heart of Midlothian | 2:0 | ||||
| 33. Round | 06/04/2013 | Heart of Midlothian | - | Ross County FC | 4:2 |
Scotland