| 7. Round | 22/09/2012 | Dundee United | - | Heart of Midlothian | 0:3 | ||||
| 10. Round | 21/10/2012 | Heart of Midlothian | - | Motherwell FC | 1:0 | ||||
| 13. Round | 10/11/2012 | Inverness CT | - | Heart of Midlothian | 1:1 |  |
|||
| 14. Round | 17/11/2012 | Heart of Midlothian | - | St. Mirren FC | 1:0 | ||||
| 15. Round | 24/11/2012 | Motherwell FC | - | Heart of Midlothian | 0:0 | ||||
| 16. Round | 28/11/2012 | Heart of Midlothian | - | Celtic FC | 0:4 | ||||
| 18. Round | 15/12/2012 | St. Johnstone FC | - | Heart of Midlothian | 2:2 | ||||
| 19. Round | 23/12/2012 | Heart of Midlothian | - | Dundee United | 2:1 | ||||
| 22. Round | 03/01/2013 | Heart of Midlothian | - | Hibernian FC | 0:0 | ||||
| 23. Round | 19/01/2013 | Celtic FC | - | Heart of Midlothian | 4:1 | ||||
| 21. Round | 02/02/2013 | Ross County FC | - | Heart of Midlothian | 2:2 | ||||
| 27. Round | 16/02/2013 | Heart of Midlothian | - | Kilmarnock FC | 0:3 | ||||
| 29. Round | 27/02/2013 | St. Mirren FC | - | Heart of Midlothian | 2:0 | ||||
| 24. Round | 02/03/2013 | Heart of Midlothian | - | Motherwell FC | 1:2 | ||||
| 32. Round | 30/03/2013 | Aberdeen FC | - | Heart of Midlothian | 2:0 | |
Australia
Scotland