| 5. Round | 14/09/2013 | Valenciennes FC | - | AS Saint-Étienne | 1:3 |  |
|||
| 6. Round | 20/09/2013 | AS Saint-Étienne | - | Toulouse FC | 1:2 | ||||
| 7. Round | 24/09/2013 | Olympique Marseille | - | AS Saint-Étienne | 2:1 |  |
|||
| 8. Round | 28/09/2013 | AS Saint-Étienne | - | SC Bastia | 2:2 | ||||
| 9. Round | 05/10/2013 | AS Monaco | - | AS Saint-Étienne | 2:1 | |
|||
| 10. Round | 20/10/2013 | AS Saint-Étienne | - | FC Lorient | 3:2 | ||||
| 11. Round | 27/10/2013 | AS Saint-Étienne | - | Paris Saint-Germain | 2:2 | ||||
| 12. Round | 02/11/2013 | FC Sochaux | - | AS Saint-Étienne | 0:0 | ||||
| 13. Round | 10/11/2013 | AS Saint-Étienne | - | Olympique Lyonnais | 1:2 | ||||
| 14. Round | 24/11/2013 | OGC Nice | - | AS Saint-Étienne | 0:1 | ||||
| 15. Round | 30/11/2013 | AS Saint-Étienne | - | Stade de Reims | 4:0 | ||||
| 16. Round | 04/12/2013 | Stade Rennais | - | AS Saint-Étienne | 3:1 | ||||
| 18. Round | 13/12/2013 | Montpellier HSC | - | AS Saint-Étienne | 0:1 | ||||
| 19. Round | 21/12/2013 | AS Saint-Étienne | - | FC Nantes | 2:0 | ||||
| 17. Round | 08/01/2014 | AS Saint-Étienne | - | Évian Thonon Gaillard | 1:0 | ||||
| 20. Round | 11/01/2014 | EA Guingamp | - | AS Saint-Étienne | 0:0 | ||||
| 21. Round | 17/01/2014 | AS Saint-Étienne | - | Lille OSC | 2:0 |
France
