| 1. Round | 03/08/2024 | Heart of Midlothian | - | Rangers FC | 0:0 | ||||
| 2. Round | 10/08/2024 | Dundee FC | - | Heart of Midlothian | 3:1 |  |
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| 3. Round | 25/08/2024 | Motherwell FC | - | Heart of Midlothian | 3:1 |  |
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| 4. Round | 01/09/2024 | Heart of Midlothian | - | Dundee United | 0:1 | ||||
| 6. Round | 28/09/2024 | Heart of Midlothian | - | Ross County FC | 1:1 | ||||
| 7. Round | 06/10/2024 | Aberdeen FC | - | Heart of Midlothian | 3:2 | |
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| 8. Round | 19/10/2024 | Heart of Midlothian | - | St. Mirren FC | 4:0 | ||||
| 9. Round | 27/10/2024 | Hibernian FC | - | Heart of Midlothian | 1:1 | ||||
| 10. Round | 30/10/2024 | Heart of Midlothian | - | Kilmarnock FC | 1:2 | ||||
| 11. Round | 02/11/2024 | St. Johnstone FC | - | Heart of Midlothian | 1:2 | ||||
| 12. Round | 10/11/2024 | Rangers FC | - | Heart of Midlothian | 1:0 | ||||
| 13. Round | 23/11/2024 | Heart of Midlothian | - | Celtic FC | 1:4 | ||||
| 14. Round | 01/12/2024 | Heart of Midlothian | - | Aberdeen FC | 1:1 |
England