| 1. Round | 10/02/2014 | River Plate | - | Gimnasia de La Plata | 1:0 | ||||
| 2. Round | 16/02/2014 | Rosario Central | - | River Plate | 1:1 |  |
|||
| 3. Round | 20/02/2014 | River Plate | - | Godoy Cruz | 1:2 | ||||
| 6. Round | 07/03/2014 | Tigre | - | River Plate | 0:0 | ||||
| 7. Round | 09/03/2014 | River Plate | - | Arsenal de Sarandí | 1:0 | ||||
| 8. Round | 17/03/2014 | All Boys | - | River Plate | 3:2 | ||||
| 9. Round | 23/03/2014 | River Plate | - | Lanús | 2:0 | |
|||
| 10. Round | 30/03/2014 | Boca Juniors | - | River Plate | 1:2 | |
|||
| 11. Round | 03/04/2014 | River Plate | - | Newell's Old Boys | 1:0 | ||||
| 12. Round | 07/04/2014 | Belgrano de Córdoba | - | River Plate | 2:1 | ||||
| 14. Round | 16/04/2014 | Estudiantes | - | River Plate | 0:0 | ||||
| 15. Round | 20/04/2014 | River Plate | - | Vélez Sarsfield | 1:0 | ||||
| 16. Round | 28/04/2014 | Olimpo de Bahía Blanca | - | River Plate | 1:1 | ||||
| 17. Round | 04/05/2014 | River Plate | - | Racing Club | 3:2 | ||||
| 18. Round | 12/05/2014 | Argentinos Juniors | - | River Plate | 0:2 |  |
|||
| 19. Round | 18/05/2014 | River Plate | - | Quilmes | 5:0 | |
Argentina
Spain 