| 1. Round | 08/09/1965 | Hibernian FC | - | Valencia CF | 2:0 |  |
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| 1. Round | 12/10/1965 | Valencia CF | - | Hibernian FC | 2:0 | ||||
| 1. Round | 03/11/1965 | Valencia CF | - | Hibernian FC | 3:0 |
| 1. Round | 08/09/1965 | Hibernian FC | - | Valencia CF | 2:0 | |
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| 1. Round | 12/10/1965 | Valencia CF | - | Hibernian FC | 2:0 | ||||
| 1. Round | 03/11/1965 | Valencia CF | - | Hibernian FC | 3:0 |
| James Scott | |
| Born: | 21.08.1940 |
| Place of birth: |
Falkirk, 
Scotland |
| Nationality: |
Scotland
|
| Position(s): | Right Winger |