| 1. Round | 23/08/2006 | Huachipato | - | Colo-Colo | 1:2 | ||||
| 1. Round | 30/08/2006 | Colo-Colo | - | Huachipato | 5:3 pso | ||||
| 2. Round | 11/09/2006 | Coronel Bolognesi | - | Colo-Colo | 2:1 |  |
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| 2. Round | 18/09/2006 | Colo-Colo | - | Coronel Bolognesi | 1:0 |  |
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| Round of 16 | 03/10/2006 | LD Alajuelense | - | Colo-Colo | 0:4 | |
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| Round of 16 | 09/10/2006 | Colo-Colo | - | LD Alajuelense | 7:2 | |
Chile