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| 1st(1st leg) | San Lorenzo | - | Banfield | 2:1 (2:0) | ||
| 2nd (2nd leg) | Banfield | - | San Lorenzo | 0:0 (0:0) | ||
| 1st(1st leg): 22/08/2006 | 2nd (2nd leg): 12/09/2006 | Winner: San Lorenzo | ||||
| 1st(1st leg) | Lanús | - | Vélez Sarsfield | 2:0 (0:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Lanús | 0:1 (0:0) | ||
| 1st(1st leg): 30/08/2006 | 2nd (2nd leg): 20/09/2006 | Winner: Lanús | ||||
| 1st(1st leg) | Libertad | - | Nacional | 1:2 (1:0) | ||
| 2nd (2nd leg) | Nacional | - | Libertad | 2:1 (1:0) | ||
| 1st(1st leg): 05/09/2006 | 2nd (2nd leg): 19/09/2006 | Winner: Nacional | ||||
| 1st(1st leg) | Deportes Tolima | - | Mineros de Guayana | 0:0 (0:0) | ||
| 2nd (2nd leg) | Mineros de Guayana | - | Deportes Tolima | 2:2 (2:2) | ||
| 1st(1st leg): 05/09/2006 | 2nd (2nd leg): 21/09/2006 | Winner: Deportes Tolima | ||||
| 1st(1st leg) | Paraná Clube | - | Athletico Paranaense | 1:3 (1:2) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Paraná Clube | 1:0 (0:0) | ||
| 1st(1st leg): 06/09/2006 | 2nd (2nd leg): 13/09/2006 | Winner: Athletico Paranaense | ||||
| 1st(1st leg) | Santos FC | - | Cruzeiro | 1:0 (0:0) | ||
| 2nd (2nd leg) | Cruzeiro | - | Santos FC | 3:4 (0:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 06/09/2006 | 2nd (2nd leg): 13/09/2006 | Winner: Santos FC | ||||
| 1st(1st leg) | Vasco da Gama - RJ | - | Corinthians SP | 0:1 (0:0) | ||
| 2nd (2nd leg) | Corinthians SP | - | Vasco da Gama - RJ | 3:1 (3:1) | ||
| 1st(1st leg): 06/09/2006 | 2nd (2nd leg): 13/09/2006 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Botafogo - RJ | - | Fluminense RJ | 1:1 (0:1) | ||
| 2nd (2nd leg) | Fluminense RJ | - | Botafogo - RJ | 4:2 (0:0, 1:1, 1:1) pso | ||
| 1st(1st leg): 07/09/2006 | 2nd (2nd leg): 14/09/2006 | Winner: Fluminense RJ | ||||
| 1st(1st leg) | Coronel Bolognesi | - | Colo-Colo | 2:1 (0:0) | ||
| 2nd (2nd leg) | Colo-Colo | - | Coronel Bolognesi | 1:0 (1:0) | ||
| 1st(1st leg): 12/09/2006 | 2nd (2nd leg): 19/09/2006 | Winner: Colo-Colo | ||||
| 1st(1st leg) | Universitario de Sucre | - | El Nacional | 1:3 (0:2) | ||
| 2nd (2nd leg) | El Nacional | - | Universitario de Sucre | 2:1 (1:1) | ||
| 1st(1st leg): 12/09/2006 | 2nd (2nd leg): 21/09/2006 | Winner: El Nacional | ||||
