| Group D | 27/09/2005 | Lille OSC | - | Villarreal CF | 0:0 | ||||
| Group D | 18/10/2005 | Villarreal CF | - | SL Benfica | 1:1 |  |
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| Group D | 02/11/2005 | SL Benfica | - | Villarreal CF | 0:1 | ||||
| Group D | 07/12/2005 | Villarreal CF | - | Lille OSC | 1:0 |  |
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| Round of 16 | 22/02/2006 | Rangers FC | - | Villarreal CF | 2:2 | |
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| Round of 16 | 07/03/2006 | Villarreal CF | - | Rangers FC | 1:1 | ||||
| Quarter-finals | 29/03/2006 | Inter | - | Villarreal CF | 2:1 | ||||
| Quarter-finals | 04/04/2006 | Villarreal CF | - | Inter | 1:0 | ||||
| Semi-finals | 19/04/2006 | Arsenal FC | - | Villarreal CF | 1:0 | |
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| Semi-finals | 25/04/2006 | Villarreal CF | - | Arsenal FC | 0:0 |
Argentina