| 8. Round | 05/10/2013 | FC Schalke 04 | - | FC Augsburg | 4:1 | ||||
| 19. Round | 01/02/2014 | FC Schalke 04 | - | VfL Wolfsburg | 2:1 | ||||
| 20. Round | 09/02/2014 | FC Schalke 04 | - | Hannover 96 | 2:0 | ||||
| 21. Round | 15/02/2014 | Bayer Leverkusen | - | FC Schalke 04 | 1:2 | ||||
| 25. Round | 14/03/2014 | FC Augsburg | - | FC Schalke 04 | 1:2 |  |
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| 26. Round | 22/03/2014 | FC Schalke 04 | - | Eintracht Braunschweig | 3:1 | ||||
| 27. Round | 25/03/2014 | Borussia Dortmund | - | FC Schalke 04 | 0:0 | ||||
| 28. Round | 28/03/2014 | FC Schalke 04 | - | Hertha BSC | 2:0 | ||||
| 29. Round | 05/04/2014 | Werder Bremen | - | FC Schalke 04 | 1:1 | |
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| 30. Round | 11/04/2014 | FC Schalke 04 | - | Eintracht Frankfurt | 2:0 | ||||
| 31. Round | 20/04/2014 | VfB Stuttgart | - | FC Schalke 04 | 3:1 | ||||
| 32. Round | 27/04/2014 | FC Schalke 04 | - | Bor. Mönchengladbach | 0:1 | ||||
| 33. Round | 03/05/2014 | SC Freiburg | - | FC Schalke 04 | 0:2 |  |
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| 34. Round | 10/05/2014 | FC Schalke 04 | - | 1. FC Nürnberg | 4:1 |
Germany