| 5. Round | 27/08/2022 | Bonnyrigg Rose Athletic | - | Stirling Albion FC | 1:0 | ||||
| 6. Round | 03/09/2022 | Stirling Albion FC | - | Albion Rovers | 1:1 | ||||
| 8. Round | 17/09/2022 | Stirling Albion FC | - | Stranraer FC | 4:1 |  |
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| 7. Round | 24/09/2022 | Forfar Athletic | - | Stirling Albion FC | 1:4 | |
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| 9. Round | 01/10/2022 | East Fife FC | - | Stirling Albion FC | 1:2 | ||||
| 10. Round | 08/10/2022 | Stirling Albion FC | - | Dumbarton FC | 6:0 | ||||
| 11. Round | 15/10/2022 | Stenhousemuir FC | - | Stirling Albion FC | 1:3 |  |
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| 12. Round | 29/10/2022 | Stirling Albion FC | - | Bonnyrigg Rose Athletic | 2:1 | ||||
| 13. Round | 05/11/2022 | Albion Rovers | - | Stirling Albion FC | 1:1 | ||||
| 14. Round | 12/11/2022 | Stirling Albion FC | - | Annan Athletic | 0:2 | ||||
| 15. Round | 19/11/2022 | Stirling Albion FC | - | East Fife FC | 3:1 | |
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| 16. Round | 03/12/2022 | Stranraer FC | - | Stirling Albion FC | 3:1 | ||||
| 18. Round | 23/12/2022 | Elgin City | - | Stirling Albion FC | 1:2 | |
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| 19. Round | 31/12/2022 | Stirling Albion FC | - | Stenhousemuir FC | 3:1 | ||||
| 22. Round | 28/01/2023 | Stirling Albion FC | - | Stranraer FC | 1:0 |
Scotland