| Group 5 | 08/02/2006 | LDU Quito | - | Vélez Sarsfield | 1:3 |  |
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| Group 5 | 15/02/2006 | Vélez Sarsfield | - | Rocha | 3:0 | |
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| Group 5 | 08/03/2006 | Universitario de Deportes | - | Vélez Sarsfield | 0:1 | |
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| Round of 16 | 28/04/2006 | Newell's Old Boys | - | Vélez Sarsfield | 2:4 |  |
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| Round of 16 | 03/05/2006 | Vélez Sarsfield | - | Newell's Old Boys | 2:2 | ||||
| Quarter-finals | 10/05/2006 | Deportivo Guadalajara | - | Vélez Sarsfield | 0:0 |
Argentina