| 1. Round | 13/09/2020 | Liverpool FC U23 | - | Everton FC U23 | 1:0 |  |
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| 2. Round | 18/09/2020 | Derby County U23 | - | Liverpool FC U23 | 2:1 | ||||
| 3. Round | 25/09/2020 | Manchester United U23 | - | Liverpool FC U23 | 3:5 |  |
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| 8. Round | 06/11/2020 | West Ham United U23 | - | Liverpool FC U23 | 2:4 | ||||
| 10. Round | 28/11/2020 | Liverpool FC U23 | - | Manchester City U23 | 2:7 | |
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| 12. Round | 19/12/2020 | Liverpool FC U23 | - | Tottenham Hotspur U23 | 3:4 | ||||
| 14. Round | 18/01/2021 | Everton FC U23 | - | Liverpool FC U23 | 1:1 | ||||
| 16. Round | 30/01/2021 | Liverpool FC U23 | - | Manchester United U23 | 3:6 | |
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| 19. Round | 19/02/2021 | Chelsea FC U23 | - | Liverpool FC U23 | 2:3 | ||||
| 18. Round | 04/04/2021 | Liverpool FC U23 | - | Brighton & Hove Albion U23 | 3:2 | ||||
| 23. Round | 09/04/2021 | Manchester City U23 | - | Liverpool FC U23 | 3:2 | ||||
| 24. Round | 19/04/2021 | Blackburn Rovers U23 | - | Liverpool FC U23 | 2:2 | |
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| 26. Round | 03/05/2021 | Liverpool FC U23 | - | Leicester City U23 | 2:2 | |
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| 13. Round | 10/05/2021 | Leicester City U23 | - | Liverpool FC U23 | 0:2 |
England