| Round of 16 | 13/07/2021 | LDU Quito | - | Grêmio Porto Alegre | 0:1 |  |
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| Round of 16 | 20/07/2021 | Grêmio Porto Alegre | - | LDU Quito | 1:2 | ||||
| Quarter-finals | 12/08/2021 | LDU Quito | - | Athletico Paranaense | 1:0 | ||||
| Quarter-finals | 19/08/2021 | Athletico Paranaense | - | LDU Quito | 4:2 |
| Lucas Ezequiel Piovi | |
| Born: | 20.08.1992 |
| Place of birth: |
Buenos Aires, 
Argentina |
| Nationality: |
Argentina
Spain |
| Height: | 170 cm |
| Weight: | 69 kg |
| Position(s): | Defensive Midfielder Central Midfielder |
| Foot: | right |
