| 5. Round | 27/08/2022 | Alloa Athletic | - | Peterhead FC | 5:0 |  |
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| 6. Round | 03/09/2022 | Clyde FC | - | Alloa Athletic | 2:4 | ||||
| 16. Round | 19/11/2022 | FC Edinburgh | - | Alloa Athletic | 4:3 | ||||
| 20. Round | 31/12/2022 | Alloa Athletic | - | Kelty Hearts | 0:0 | ||||
| 24. Round | 04/02/2023 | Alloa Athletic | - | Peterhead FC | 1:0 | ||||
| 18. Round | 07/02/2023 | Alloa Athletic | - | Falkirk FC | 1:1 | ||||
| 30. Round | 25/03/2023 | Peterhead FC | - | Alloa Athletic | 0:2 | ||||
| 33. Round | 15/04/2023 | Kelty Hearts | - | Alloa Athletic | 0:1 | ||||
| 34. Round | 22/04/2023 | Alloa Athletic | - | Falkirk FC | 1:4 | ||||
| 35. Round | 29/04/2023 | Montrose FC | - | Alloa Athletic | 0:4 | ||||
| 36. Round | 06/05/2023 | Alloa Athletic | - | Dunfermline Athletic | 0:2 |
Scotland