| 1. Round | 04/08/2013 | Gimnasia de La Plata | - | River Plate | 1:0 | ||||
| 2. Round | 10/08/2013 | River Plate | - | Rosario Central | 1:0 | ||||
| 3. Round | 19/08/2013 | Godoy Cruz | - | River Plate | 0:0 | ||||
| 4. Round | 25/08/2013 | River Plate | - | Colón de Santa Fe | 1:2 | ||||
| 5. Round | 02/09/2013 | San Lorenzo | - | River Plate | 1:0 | ||||
| 6. Round | 08/09/2013 | River Plate | - | Tigre | 3:0 |  |
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| 7. Round | 16/09/2013 | Arsenal de Sarandí | - | River Plate | 1:1 | ||||
| 8. Round | 23/09/2013 | River Plate | - | All Boys | 1:0 | ||||
| 9. Round | 30/09/2013 | Lanús | - | River Plate | 0:1 | ||||
| 10. Round | 06/10/2013 | River Plate | - | Boca Juniors | 0:1 | ||||
| 11. Round | 14/10/2013 | Newell's Old Boys | - | River Plate | 1:0 |  |
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| 12. Round | 20/10/2013 | River Plate | - | Belgrano de Córdoba | 0:0 | ||||
| 13. Round | 23/10/2013 | Atlético Rafaela | - | River Plate | 0:0 | ||||
| 16. Round | 17/11/2013 | River Plate | - | Olimpo de Bahía Blanca | 1:3 | ||||
| 17. Round | 25/11/2013 | Racing Club | - | River Plate | 1:0 | ||||
| 18. Round | 02/12/2013 | River Plate | - | Argentinos Juniors | 1:0 | ||||
| 19. Round | 09/12/2013 | Quilmes | - | River Plate | 1:1 |
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