| 1. Round | 05/08/2006 | Barnsley FC | - | Cardiff City | 1:2 | ||||
| 2. Round | 08/08/2006 | Hull City | - | Barnsley FC | 2:3 |  |
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| 3. Round | 12/08/2006 | Colchester United | - | Barnsley FC | 1:2 | ||||
| 4. Round | 19/08/2006 | Barnsley FC | - | Southampton FC | 2:2 | ||||
| 5. Round | 26/08/2006 | Norwich City | - | Barnsley FC | 5:1 | ||||
| 6. Round | 09/09/2006 | Barnsley FC | - | Stoke City | 2:2 | ||||
| 7. Round | 12/09/2006 | Burnley FC | - | Barnsley FC | 4:2 | |
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| 8. Round | 16/09/2006 | Barnsley FC | - | Wolverhampton Wanderers | 1:0 |  |
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| 9. Round | 22/09/2006 | Preston North End | - | Barnsley FC | 1:0 | ||||
| 10. Round | 30/09/2006 | Barnsley FC | - | Luton Town | 1:2 | ||||
| 11. Round | 14/10/2006 | Sheffield Wednesday | - | Barnsley FC | 2:1 | ||||
| 12. Round | 17/10/2006 | Barnsley FC | - | Plymouth Argyle | 2:2 | |
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| 13. Round | 21/10/2006 | Sunderland AFC | - | Barnsley FC | 2:0 | ||||
| 14. Round | 28/10/2006 | Barnsley FC | - | Coventry City | 0:1 | ||||
| 15. Round | 01/11/2006 | Derby County | - | Barnsley FC | 2:1 | ||||
| 16. Round | 04/11/2006 | Barnsley FC | - | Leeds United | 3:2 | |
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| 17. Round | 11/11/2006 | Birmingham City | - | Barnsley FC | 2:0 | ||||
| 18. Round | 18/11/2006 | Crystal Palace | - | Barnsley FC | 2:0 |
Scotland